Abstract
Abstract Comparison of the homogeneous and heterogenizing homogeneous cobalt ion catalyst in the synthesis of organic peroxides was studied. The heterogenizing or immobilizing homogeneous cobalt ion catalyst was prepared by ion exchange of the cobalt ion on a polymer support. Acetaldehyde was used as the model compound for the comparison of the homogeneous and the heterogenizing homogeneous catalyst. The results indicate that both the selectivity and yield of peracetic acid by using the heterogenizing homogeneous catalyst is higher than that of using a homogeneous catalyst. The comparison of the reaction mechanism as well as the kinetics of using these two types of catalysts were also obtained.
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