Abstract

We present a study of the electronic structure of the organic semiconductor copper tetrafluorophthalocyanine (CuPCF 4 ) deposited on the inert Au(100) and on the reactive indium-tin oxide (ITO) surfaces using photoemission spectroscopy. Whereas the Fermi level of the organic on gold is approximately in the mid-gap position, the strong chemical interaction between the molecules and ITO causes interface states resulting in a shift of the Fermi level at the interface towards the lowest unoccupied molecular orbital.

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