Comparison of surface tension, density, viscosity and contact angle of ethyl oleate to those of ethanol and oleic acid

Abstract

Taking into account extensive practical application of ethyl oleate (EO) some of its physicochemical properties were determined and compared to those of ethanol (ET) and oleic acid (OA). For this purpose the surface tension, density, viscosity and contact angle of EO, ET and OA were measured. The contact angle was measured on the polytetrafluoroethylene (PTFE), poly(methyl methacrylate) (PMMA), steel and glass in the solid–liquid–air system. Based on the results of the surface tension and contact angle of ET, EO and OA on PTFE and PMMA the Lifshitz-van der Waals component as well as electron-acceptor and electron-donor parameters of the acid-base component of surface tension of these liquids were determined. For this determination the van Oss et al. method was applied. This method was carefully analyzed in terms of its usefulness for the systems studied by us. The components and parameters of the ET, EO and OA surface tension were analyzed with regard to their molecular structure. Based on the molecular structure and on the length of bonds and contact angle between them the size of the molecules and their contactable area were determined.