Abstract
In this study, the pollution status of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) was investigated in indoor and outdoor dust from three different functional areas of Hefei, China. The relationship between the concentrations of PCBs and OCPs and different influencing factors in dwellings was studied. The results showed that the concentrations of PCBs and OCPs were higher in samples from dwellings with higher smoking frequency, lower cleaning frequency, higher floors and smaller household size. The results of Spearman's correlation coefficient analysis indicated that PCBs and OCPs were not consistently associated with each other, while sources of low-chlorinated PCBs and high-chlorinated PCBs were different. Scanning electron microscopy (SEM) shows the shape of indoor dust was a mixture of blocky, flocculated, spherical structures, and irregular shapes. The results of principal component analysis (PCA) and positive matrix factorization model (PMF) showed that the PCBs and OCPs of indoor dust came from both indoor and outdoor sources between local and regional transport. Carbon (δ13C) and Nitrogen (δ15N) stable isotope results indicate or show that the indoor dust (δ13C: - 24.37‰, δ15N: 6.88‰) and outdoor dust (δ13C: - 12.65‰, δ15N: 2.558‰) is derived from fossil fuel, coal combustion, road dust, fly ash, C4 biomass and soil. Potential source contribution factor (PSCF) and concentration weighted-trajectory analysis suggest that sources of pollutants were local and regional transport from surrounding provinces and marine emissions. The average daily dose (adult: 8.20E-04, children: 2.37E-03) of pollutants and the carcinogenic risks (adult: 1.23E-02, children: 2.65E-02) were relatively greater for children than adults. This study demonstrates the utility of SEM to characterize indoor dust morphology while combining PMF, PSCF, and stable isotope methods in identifying indoor PCBs and OCPs sources and regions.
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