Comparison of omniphobic membranes and Janus membranes with a dense hydrophilic surface layer for robust membrane distillation

Abstract

Membrane wetting, fouling, and scaling are three prominent challenges that limit membrane distillation (MD) applications. To overcome these challenges, novel MD membranes including omniphobic membranes and Janus membranes with a dense hydrophilic surface layer have been developed. In this study, we fabricated an omniphobic membrane and a Janus membrane composed of a dense polyvinyl alcohol (PVA) surface layer and a polyvinylidene fluoride (PVDF) substrate. The two membranes have been compared in MD experiments with different feeds. Furthermore, the working mechanisms of the two membranes have been elucidated. As a result, neither the omniphobic MD membrane nor the Janus MD membrane can resolve all three challenges at the same time. Specifically, both the omniphobic MD membrane and Janus MD membrane can resist wetting but via different working mechanisms. From breakthrough pressure (BP) determinations with an ethanol-water mixture (i.e., a low-surface-tension liquid), the omniphobic MD membrane resists wetting as its LEP (82.0 ± 9.2 kPa) is larger than the transmembrane pressure in the MD operation, while the Janus MD membrane resists wetting because the huge capillary pressure (550 ± 50 kPa) in the dense hydrophilic surface layer retains the wetting solution. The omniphobic MD membrane is prone to oil fouling because of the strong underwater hydrophobic attraction between the membrane surface and the mineral oil droplets, while the Janus MD membrane can substantially mitigate fouling due to the lack of attraction between the mineral oil droplets and the hydrophilic membrane surface. The omniphobic MD membrane exhibits outstanding scaling resistance because minerals can hardly precipitate and/or crystalize on the membrane surface, while the Janus MD membrane was susceptible to scaling due to the precipitation and/or crystallization of minerals inside the hydrophilic surface layer. Therefore, the selection of MD membranes should depend on the feed constituents. Overall, our study provides important guidelines for the future development of robust MD membranes.