Comparison of magnetocaloric properties from magnetic and thermal measurements

Abstract

The isothermal change of the magnetic entropy of a magnetically ordered material upon application of external magnetic field can be calculated from the temperature and field dependence of the magnetization or of the specific heat. The adiabatic temperature change, i.e., the magnetocaloric effect (MCE) can be measured directly or can be calculated via different methods using the field-dependent specific heat values, or a combination of data obtained via magnetization and thermal measurements. In the present study, magnetic and thermal measurements were carried out on Gd75Y25(TC=232 K) and Gd48Y52(TC=161 K) samples, for applied fields ranging between 0 and 7 T. From both datasets, the magnetic entropy change and MCE values were calculated and compared, in order to assess the mutual reliability of the methods applied. The magnetically or thermally deduced specific heat discontinuities show a reasonable agreement within experimental error. Similar comparison of the calculated magnetic entropy changes reveals that the measured transition temperature and the shape of the curve do not depend on the method selected. It is demonstrated that the choice of an integration constant during entropy calculation has a significant impact on the adiabatic temperature change deduced from the field and temperature dependence of the entropies. For the MCE, a better approximation can be obtained using the magnetically acquired magnetic entropy change and the field-dependent specific heat. The results prove that magnetic measurements carried out in high enough magnetic fields provide reliable information on the isothermal magnetic entropy change and, when combined with field-dependent specific heat measurements, on the magnetocaloric effect as well.