Abstract

On the basis of high-precision measurements of the retention times of alkylbenzene, the accuracies of the determinations of linear and logarithmic retention indices were compared, and the correlation between the structure and the retention of isomers of these two interpolation characteristics was investigated. The linear retention index can be measured more accurately than the logarithmic value. Fine correlations between structure and retention are different for the two types of retention indices; logarithmic retention indices are more suitable for these correlations.

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