Abstract
Herein, we compared thermal desorption analysis (TDA) curves obtained by conducting experiments and simulations. In addition, we discussed the validation of our simulations and trapping sites of hydrogen atoms. In as-received F82H, when the samples contained solute atoms, grain boundaries, dislocations, and precipitates, the experimental curve corresponded to the simulated curve. In positron annihilation lifetime (PAL) measurements, di-vacancies were detected in the electron-irradiated F82H. When we changed the growth and the concentration of vacancy-type defects during temperature increase using the rate theory, the simulation results agreed with experiment results. In creep-ruptured Fe, only dislocations were detected by the PAL measurements. However, the existence of a type of defect, which was related to grain boundaries, must be assumed to fit the simulation curve to the experimental one. In the next step, the diffusion of hydrogen atoms on grain boundaries should be added to simulation program.
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