Abstract
Redox catalysis has been used to investigate the homogeneous electron-transfer reactions between the substrates (nitroalkane or diketone) and the reduced form of the catalyst, which was terephthalonitrile. The substrates were RNO 2 (R=Me, Et, i-Pr, and t-Bu) and RC(O)C(O)R (R=Me, Et, and t-Bu). The experiments were conducted in acetonitrile solvent at 298 K with three different electrolytes, R 4 NClO 4 (R=Et, n-Bu, and n-C 7 H 15 )
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