Abstract

Abstract. This paper compares total ozone measurements from five Brewer spectroradiometers located at the Iberian Peninsula with satellite observations given by the GOME (Global Ozone Monitoring Experiment) sensor. The analyzed period covers simultaneous ozone values from July 1995 until December 2004. The regression analysis shows an excellent agreement between Brewer-GOME values in the five locations; the coefficient of correlation is always higher than 0.92 and the root mean square error is about 3%. Moreover, the comparison shows that the satellite retrieval accuracy is within the uncertainty of current ground-based instruments. In addition, the effects of several variables, such as cloudiness, solar zenith angle (SZA), effective temperature and total ozone values in Brewer-GOME differences are analyzed. The results indicate that clouds induce a minor dependence of GOME values on the SZA. For example, during heavy cloudy conditions in Madrid station, GOME observations overestimate ground-based Brewer data for low AMF (low SZA values) by 2% while for high AMF (high SZA values) the satellite underestimates ground-based ozone values by 1%. Moreover, the dependence of Brewer-GOME differences with respect to SZA for cloud-free conditions may be due to the variability of effective temperature. This fact could indicate that the effective temperature estimated by GOME does not fully reflect the actual atmospheric temperature variability. Finally, GOME ozone observations slightly underestimate the highest values measured by the Brewer spectrophotometers and overestimates the lowest ground-based measurements.

Highlights

  • Satellite monitoring of the Earth’s atmosphere allows one to globally record spatial and temporal information on different physical parameters

  • To further analyse the differences between the Global Ozone Monitoring Experiment (GOME) and Brewer observations, we examined the temporal evolution of the differences and the dependence on cloudiness, solar zenith angle (SZA), effective temperature and total ozone amount

  • Some important conclusions may be drawn from the GOMEBrewer comparison over five locations in the Iberian Peninsula

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Summary

Introduction

Satellite monitoring of the Earth’s atmosphere allows one to globally record spatial and temporal information on different physical parameters. This information is required for different applications, such as climate change, numerical weather prediction and pollution monitoring. One particular area where satellite monitoring has proven to be useful is in analysing global atmospheric ozone. Accurate ozone observations from remote sensing instruments play an important role in ozone trend analysis in order to assess current and future changes in the atmosphere. GOME has proven suitable for the generation of longterm data sets of trace atmospheric constituents; a series to be extended with GOME-2, launched in October 2006, on board METOP-1

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