Comparison of compressive strength and electrical resistivity of cementitious composites with different nano- and micro-fillers

Abstract

Cementitious composites with 0–1.5wt.% Nano-SiO2 (NS), nano-TiO2 (NT), carbon nanotubes (CNTs), carbon nanofibers (CNFs) and carbon microfibers (CFs) are fabricated and tested. The enhancing effects of different fillers on the compressive strength and electrical resistivity of composites are compared, and the underlying modification mechanisms of fillers to composites are investigated by analyzing the difference in the morphology of fillers and rheology of composites. The compressive strength of composites containing 0.1% NS, 0.5% NT, 0.1% CNTs and 0.5% CFs by weight of cement presents approximately 12.5%, 20.8%, 16.8% and 21.4% higher than that of control sample, respectively. It is revealed that CFs also have improving effect on the compressive strength of composites besides flexural strength. When the composites with nano-fillers cannot be processed to ideal state, the reinforcing effect of nano-fillers is no better but even worse than that of micro-fillers. Composites with CNTs, CNFs and CFs possess good electrical conductivity. Composites with CNFs and CFs have a percolation threshold of electrical resistivity below 0.5%, while the percolation threshold of electrical resistivity of composites with CNTs is about 1%. Although CNFs do not have significant effect on compressive strength of composites, they have the best improvement to electrical resistivity.