Abstract
A series of Co-xCe/CeO2 and Ni-xCe/CeO2 catalysts with different ceria amount introduced from Ce(NO3)3 × 6H2O precursor, corresponding to Ce/Co(Ni) molar ratio from 0 to 1 were prepared by impregnation method. Among the tested catalysts, Co-0.1Ce/CeO2 and Ni-0.1Ce/CeO2 samples exhibited the smallest metal crystallites size, the strongest metal-support interaction, the best catalytic performance and the strongest resistance toward carbon deposition. Only an introduction of small amount of ceria from Ce(NO3)3 × 6H2O precursor led to an increase in the number of active sites for breaking CC and CH bonds. Too high Ce/Co molar ratio caused rapid deactivation of cobalt-based catalysts because of faster coverage of active sites by encapsulating carbon. Whereas too high Ce/Ni molar ratio generated the thick and long carbon filamentous deposits causing the nickel-based catalysts deactivation including not only the coverage of nickel species by carbon but also limitation of the contact of reactants with nickel species.
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