Abstract
Photoelectron spectra and the autoionization portion of the Auger spectra are compared for CO. Eight final states of the photoelectron spectra coincide with those of the autoionization spectra: three of them are the well-known one-hole states and the other five are two-hole—one-electron states. A photoelectron band at 27.4 eV is identified for the first time by its exact match to the strongest band of the autoionization spectra. The symmetries of these and other two-hole—one-electron states are induced by comparing the intensifies of X-ray and UV photoelectron spectra.
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