Comparison of Alternative Diesel Fuels with the Composition-Explicit Distillation Curve Method

Abstract

In recent years, environmental considerations, the potential for supply disruptions, and rising fuel prices have led to the development of alternative diesel fuels produced from nonpetroleum feedstocks. It is important to characterize the properties of these fuels in order to assess the degree of departure of the alternative fuels from the petroleum-derived fuels. One of the most important properties to use for this purpose is the volatility, as expressed by the distillation curve. In this paper, we present advanced distillation curve measurements of three prototype alternative diesel fuels and compare the distillation curve, composition, and combustion enthalpy to those of petroleum-derived diesel fuel. We studied two Fischer–Tropsch diesel fuels, one synthesized from coal-derived gas and one produced from natural gas, and one renewable diesel fuel composed of hydrotreated animal and vegetable fats. We found that the distillation curves of the three alternative diesel fuels are similar to those of petrol...