Comparison and optimization of biomass-derived hard carbon as anode materials for sodium-ion batteries

Abstract

Hard carbon made from biomass-based precursors has many advantages as anode for sodium-ion batteries such as low cost and sustainability. In this work, three different hard carbon materials derived from bamboo, wood and coconut shell with the same particle size are screened, combining acid etching and carbonization at 1200 °C, to compare the sodium ion storage performances. The anode material originated from bamboo shows the highest specific capacity among them. Subsequently, the hard carbon from bamboo is optimized by the same process, but changing the carbonization temperature ranging from 1000 °C to 1400 °C. Among the hard carbon materials, the bamboo-derived one prepared at 1300 ℃ exhibits excellent electrochemical performances at a current density of 30 mA g−1, with a high reversible specific capacity of 303.8 mAh/g and an initial coulombic efficiency of 83.7 %. After 150 cycles, a capacity retention of 94.7 % is achieved at a current density of 300 mA g−1. This work provides a potential hard carbon anode for sodium-ion batteries to realize large-scale energy storage due to the cheap sources of bamboo.