Comparing Microscopic and Macroscopic Dynamics in a Paradigmatic Model of Glass-Forming Molecular Liquid.

Abstract

Glass transition is a most intriguing and long-standing open issue in the field of molecular liquids. From a macroscopic perspective, glass-forming systems display a dramatic slowing-down of the dynamics, with the inverse diffusion coefficient and the structural relaxation times increasing by orders of magnitude upon even modest supercooling. At the microscopic level, single-molecule motion becomes strongly intermittent, and can be conveniently described in terms of “cage-jump” events. In this work, we investigate a paradigmatic glass-forming liquid, the Kob–Andersen Lennard–Jones model, by means of Molecular Dynamics simulations, and compare the macroscopic and microscopic descriptions of its dynamics on approaching the glass-transition. We find that clear changes in the relations between macroscopic timescales and cage-jump quantities occur at the crossover temperature where Mode Coupling-like description starts failing. In fact, Continuous Time Random Walk and lattice model predictions based on cage-jump statistics are also violated below the crossover temperature, suggesting the onset of a qualitative change in cage-jump motion. Interestingly, we show that a fully microscopic relation linking cage-jump time- and length-scales instead holds throughout the investigated temperature range.