Comparing desorption properties of pollutants on bentonite particles and in compacted bentonite

Abstract

Desorption is one of the main factors causing groundwater and soil pollution. Therefore, the study of clay desorption characteristics is important for the prediction of groundwater and soil pollution. In previous studies, batch tests and column tests were used to study the desorption characteristics of pollutants on clay. However, the desorption parameters obtained via the two test methods were often quite different. To investigate differences in the desorption characteristics of different pollutants on clay particles and in compacted clay, batch and column desorption tests were conducted using cadmium chloride, fulvic acid, and sodium phosphate as the adsorbates and bentonite as the adsorbent. It was found that the unit particle surface area desorption distribution coefficients of pollutants on bentonite particles were approximately equal to the unit pore surface area distribution coefficients of pollutants in compacted bentonite. This indicates that the desorbed amount per unit of surface area is basically consistent, regardless of whether they are sorbed on particles or in compacted bentonite. A simple formula for determining the desorption retardation factor of pollutants in compacted bentonite is presented. The results of this study provide a reference for the prediction and evaluation of groundwater and soil pollution.