Abstract
This work attempts to understand the effect of initial conditions, i.e., as-milled powder and phase stabilized nearly single phase powder (through annealing), on sintering kinetics of CoCrFeNi high entropy alloy powders. Dilatometric study indicates, axial shrinkage reduced from about 5% to 3% when powder was annealed. Analysis of shrinkage through non-isothermal method shows activation energies of sintering increased significantly for a given model, in annealed powder compared to as-milled powder. Calculated activation energies indicate, in as-milled powder grain boundary diffusion seems to be the dominating mechanism, attributed to the presence of ultrafine grains and a large fraction of grain boundaries. On the other hand, annealing helped to form almost single phase HEA, decrease in defect concentration and reduced grain boundary fraction with increased crystallites; which led to increase in activation energies. Coefficients of thermal expansion have also been studied and it was found to vary with temperature range.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.