Abstract

Vanadium dioxide (VO2) thin films were fabricated by means of DC reactive magnetron sputtering at low temperature, and then were aged in air for 5 years. The thermochromic properties of the fresh VO2 film and aged one were investigated by UV–visible spectrophotometer. The experimental results show that the fresh VO2 film shows excellent thermochromic properties with a high visible transmittance of 40.8% and a large switching efficiency of 73% at 2500 nm. For the film aged in ambient air for 5 years, the visible transmittance is increased to 54.0% due to a blue-shift of absorption edge and a decrease in luminous absorbance. More interestingly, the aged VO2 film still keeps a relatively large switching efficiency of 51% at 2500 nm, suggesting the deposited VO2 film has a good thermochromic stability in ambient air. These characteristics indicate the practical applications of VO2 film to smart optical devices.

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