Comparative study of the structure and mechanical properties of starch aerogels fabricated from air-classified and isolated pulse starches

Abstract

Significant amounts of starch and protein are generated as co-products during fractionation of pulse seeds. While pulse proteins (PP) have garnered a lot of interest in numerous applications, little attention is shown to pulse starch (PS). The creation of novel materials such as bioplastics could revolutionize the use of pulse starches. In this study, we investigated the prospects of air-classified and isolated pea, lentil, and faba bean starches as a precursor for fabricating pulse starch bioaerogels (PSBs) via freeze-drying technique. The results evidenced ultra-low densities (<0.1 m2/g), mesopore sizes (2−50 μm), high porosities (∼99 %), low surface areas (SBET = ∼4−18 m2/g) for all the aerogels. The adsorption isotherm showed typical Type II and III profiles, while the thermogravimetric analysis showed more weight loss (74.39−78.12 %) in aerogels mostly developed from isolated starches. Microstructural studies showed a unique distribution of pores within the developed aerogels. FTIR and XPS studies confirmed the presence of an amide (I, II, III) at different absorption bands range (∼1600–1200 cm−1) and functional groups (carboxylic group and the amide group), respectively. All the PSBs became stiffer with a corresponding increase in load, and a reversible deformation in the linear region was identified at <5 % strain. Comparatively, saturated PSBs from air-classified starch at a relative humidity of 95 % showed a drastic reduction in their compressive moduli (CM), while PSBs from isolated starch experienced markedly high CM. Moisture saturation was achieved at 72 h for all the samples. This study provides crucial information that could spark a keen interest in the use of non-conventional starch for the creation of novel and sustainable biobased products with expanded applications.