Abstract
1. A study was made of the dependence of the frequencies of the completely symmetric metal-ring and metal-carbonyl stretching vibrations in cyclopentadienylmanganese tricarbonyl and cyclopentadienyl-rhenium tricarbonyl derivatives on the character of the substituent in the cyclopentadienyl ring. 2. The different type of frequency shifts for the manganese and rhenium derivatives is explained by the substantially greater role of dative interaction in the formation of the metal-ring bond for the cyclopentadienylmanganese tricarbonyl derivatives.
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