Abstract

This work evaluates the behavior of a martensitic stainless steel (AISI 410) thermally treated by quenching and tempering with a tungsten carbide (86WC-10Co-4Cr) coating obtained by high-velocity oxygen fuel (HVOF) thermal spray deposition, analyzing the volume loss under erosive attacks at 30 ∘ and 90 ∘ incidence angles by using jet slurry erosion equipment with electrofused alumina erodent particles. Firstly, the characterization of the samples was carried out in terms of the microstructure (SEM), thickness, roughness, porosity, and microhardness. Then, samples were structurally characterized in the identification of the phases (XRD and EDS) present in the coating, as well as the particle size distribution (LG) and morphology of the erodent. It was determined that the tungsten carbide coating presented better resistance to jet slurry erosion wear when compared to the martensitic stainless steel analyzed, which is approximately two times higher for the 30 ∘ angle. The more ductile and brittle natures of the substrate and the coating, respectively, were evidenced by their higher volumetric erosion at 30 ∘ for the first and 90 ∘ for the latter, as well as their particular material removal mechanisms. The enhanced resistance of the coating is mainly attributed to its low porosity and high WC-Co content, resulting in elevated mechanical resistance.

Highlights

  • The erosion of metallic materials due to slurry erosion is a recurrent and common problem in various industrial applications, such as hydraulic turbines for hydroelectric plants and mud pumps, as well as the processing of minerals and pipes for the petrochemical industry

  • The lack of identification of the Co peak by X-ray diffraction (XRD) in this figure is justified by the low content of the metal in the coating, and its diffraction peak is most likely situated among the noise range in the graph

  • An experimental wear simulation equipment of jet slurry erosion was developed with conditions that allowed for the control of the significant test parameters, such as impact angle, impact velocity, erosive particle concentration in the suspension, and test temperature

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Summary

Introduction

The erosion of metallic materials due to slurry erosion is a recurrent and common problem in various industrial applications, such as hydraulic turbines for hydroelectric plants and mud pumps, as well as the processing of minerals and pipes for the petrochemical industry. Metals 2019, 9, 600 failures by erosion and corrosion, providing adequate dimensioning of parts and relying on optimized properties aggregated by the coatings. Some of the most relevant ones are martensitic stainless steels, given their wide range of industrial applications. These are commonly adopted for regular ends, such as in the automotive industry [3], but may be used in the cutting-edge design of complex structures, such as nuclear reactors [4] and power plants [5]. Martensitic stainless steels are high-carbon-content alloys (0.1–1.2%) with chromium (12–18%), presenting magnetic properties, elevated strength, low-temperature toughness, and good corrosion resistance [6], as well as better mechanical resistance to erosive particles than austenitic steel [7]

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