Abstract
A MoSi2 coating was prepared on the Mo1 wire mesh via pack cementation method, and its failure mechanisms under isothermal oxidation and hot-fire test using a hydroxylammonium nitrate based monopropellant were comparatively studied. Under isothermal oxidation at 1300 °C and 1400 °C, degradation of MoSi2 into Mo5Si3 caused failure of the coating, and interdiffusion made a much larger effect relative to oxidation. However, the MoSi2 coating failed because of the synergy of oxidation, ablation, and interdiffusion under hot-fire test. Besides, dissolution of mullite into SiO2 and ablation of high velocity flame contributed to the failure of the coating as well.
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