Abstract

The article presents the results of a study of the influence of ash content of coal on the qualitative characteristics of their IR spectra. Comparative analysis of the IR spectra of the initial and demineralized bituminous coals showed that the mineral components present in their composition in the form of silicates, clay minerals, and carbonates limit the resolution of the method in the range <970 cm-1, since their characteristic peaks are superimposed on the lines from organic matter of coal. Treatment of coals with mineral acids leads to a decrease in their ash content by 5-8 times, which results in an increase in the content of conventional organic matter in demineralized samples. This, in turn, leads to an increase in the optical density of absorption bands in the entire range of the study and, therefore, allows them to be identified more reliably.

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