Comparative study for removal of cationic and anionic dyes using alginate-based hydrogels filled with citric acid-sawdust/UiO-66-NH2 hybrid

Abstract

Nowadays, a big challenge is developing a sustainable and effective method for removing contaminants like dyes from aqueous solutions. In this regard, Zr-based metal-organic framework (UiO-66-NH2) and sawdust as the ideal adsorbents were used. Due to their low separation in adsorption processes, embedding into alginate and obtaining composite beads are suggested as a suitable strategy. The achieved Ca-alginate/citric acid (CA)-sawdust/UiO-66-NH2 hydrogel beads were used to compare cationic and anionic dyes removal. This sorbent indicated an excellent selectivity for removing methylene blue versus methyl orange in a binary system. pH = 6, adsorbent amount = 80 mg, methylene blue concentration = 10 mg/L, and contact time = 420 min were achieved as optimal parameters on methylene blue adsorption with an adsorption capacity of about 26 mg/g. The removal process of methylene blue followed linear Freundlich isotherm and nonlinear pseudo-2nd-order kinetic models. The regeneration test demonstrated methylene blue removal efficiency higher than about 89 % after 9 cycles. According to the outcomes, methylene blue could be attached to the adsorbent surface through the electrostatic, hydrogen bonding, and π-π interactions of the aromatic rings. These results confirm the potential of Ca-alginate/CA-sawdust/UiO-66-NH2 hydrogel beads as a selective bio-sorbent for cationic dye removal.