Comparative study between fluidized bed and fixed bed reactors in methane reforming combined with methane combustion for the internal heat supply under pressurized condition

Abstract

The effect of catalyst fluidization on the conversion of methane to syngas in methane reforming with CO 2 and H 2O in the presence of O 2 under pressurized conditions was investigated over Ni and Pt catalysts. Methane and CO 2 conversion in the fluidized bed reactor was higher than those in the fixed bed reactor over Ni 0.15Mg 0.85O catalyst under 1.0 MPa. This reactor effect was dependent on the catalyst properties. Conversion levels in the fluidized and fixed bed reactor were almost the same over MgO-supported Ni and Pt catalysts. It is suggested that this phenomenon is related to the catalyst reducibility. On a catalyst with suitable reducibility, the oxidized catalyst can be reduced with the produced syngas and the reforming activity regenerates in the fluidized bed reactor. Although serious carbon deposition was observed on Ni 0.15Mg 0.85O in the fixed bed reactor, it was inhibited in the fluidized bed reactor.