Abstract

New peroxo complexes of molybdenum (VI) and uranium (IV) have been prepared. The complexes were characterized on the basis of elemental analyses, conductivity measurements, magnetic measurements, infrared spectral studies and by reactions with allyl alcohol, triphenylphosphine and triphenylarsine. The complexes of U (VI) showed strong activity against both the gram positive and gram negative bacteria than the other complexes indicating the higher zone of inhibition. The present findings of MIC experiment showed that the complex 3 of U (VI) was more potent against all the bacteria tested than the other complex. Results showed that the complex 2 of Mo (VI) exhibits more toxic to brine shrimp compared to other complexes of Mo (VI) and U (VI) indicating the lower values of LC50 and LC99 for both the exposure 16h and 36h.

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