Abstract
AbstractSBA‐15 is synthesized using triblock copolymer Pluronic P123 as the structure directing agent and different silica sources such as tetraethyl orthosilicate (TEOS), sodium metasilicate, coal fly ash (CFA) derived supernatant and a mix of sodium metasilicate, CFA‐derived supernatant for comparative study towards Fischer‐Tropsch synthesis (FTS). The active metal cobalt (15 wt. %) has been impregnated in each support via the wet impregnation technique. The catalysts and supports are characterized by N2 adsorption‐desorption, Field Emission Scanning Electron Microscopy (FESEM), High‐Resolution Transmission Electron Microscopy (HRTEM), X‐ray Diffraction (XRD), X‐ray Energy Dispersion Spectrophotometer (EDX), Fourier Transform Infrared (FTIR), and Temperature Programmed Reduction (TPR). The catalytic performance of synthesized catalysts for the FTS has been investigated in a fixed bed tubular reactor at T=220 °C, P=30 bar, and GHSV=500 h−1 using simulated syngas composition equivalent to coal‐derived syngas using air blown fixed bed gasifier having H2/CO molar ratio of 2 : 1. The maximum CO conversion and middle distillate (C6−C20) selectivity is observed as 59.2 % and 84.6 % respectively for the catalyst support synthesized from mix of sodium metasilicate and CFA‐derived supernatant.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
