Comparative electrochemical investigation for scheelite structured metals tungstate (MWO4 (M = Ni, Cu and Co)) nanocubes for high dense supercapacitors application

Abstract

Scheelite structured metal tungstate MWO4 (M = Ni, Cu and Co) nanocubes were synthesized through the chemical reflux for supercapacitors application and ceyltrimethylammonium bromide (C-TAB) as surfactant. In X-ray diffraction (XRD) result are fit with relevant JCPDS cards, synthesized materials are closely matched with monoclinic and triclinic crystal phase corresponding to NiWO4, CoWO4 and CuWO4 with Scheelite type structure. To resist the growth of the particles and succeeding nanocubes morphology were achieving by using PEG-400 and C-TAB act as a surfactant. The prepared modified electrodes were examined electrochemical analysis after successive coating of working material in empty Ni foil. From the galvanostatic charge-discharge (GCD) comparative analysis, fast ions movements are interacts through the aqueous electrolyte medium with nanocubes NiWO4 electrode are achieving specific capacitance of 1185 Fg−1 at 0.5 Ag−1 and cyclic stability 93.084 % (retentivity) formerly compare to CuWO4 and CoWO4 electrodes.