Abstract

A comparative analysis including modeling and experimental evaluation of a spalling process of silicon (Si) substrates was accomplished to define the optimum condition for uniform spalling. The residual stresses in Nickle (Ni) films on Si substrates have been evaluated. Different thicknesses of Ni films electroplated on Si(100) and Si(111) substrates have been used to predict the steady-state spalling depth and crack propagation direction. This study focuses on identifying the key variables; including the Ni film thickness (h) and critical stress needed to peel-off uniform thin layers from a Si substrate. The residual stresses (thermal and epitaxial) in the Ni films have been evaluated through experiment and modeling analysis to distinguish the sources of stress generation. Different thicknesses of spalled films from Si substrates were defined to investigate the influence of the stress intensity factors (KI, KII and KIII) and the energy release rate (J1) on the steady state spalling process. Finally, the critical normal stress (σII) versus h has been determined to predict the spalling depth with uniform thickness.

Highlights

  • The flexible films are a demand in numerous applications, such as in electronic components,[1] organic light-emitting diodes,[2] energy storage devices[3] and in solar cells,[4] etc

  • Spalling is a fracture mechanism that occurs beneath the interface of a film/substrate system that possesses a residual stress (σ) exceeding the cohesive strength of the material at an atomic level

  • There are different sources generating residual stresses in the thin-film/substrate system that might occur due to the joining of different materials

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Summary

Introduction

The flexible films are a demand in numerous applications, such as in electronic components,[1] organic light-emitting diodes,[2] energy storage devices[3] and in solar cells,[4] etc. Alhomoudia National Nanotechnology Research Center, King Abdulaziz City for Science and Technology (KACST), Riyadh 11442, Saudi Arabia (Received 21 December 2016; accepted 26 February 2017; published online 8 March 2017)

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