Abstract
The apparent molar volumes of both 1,2‑propylene glycol and dimethyl sulfoxide calculated by Yang and coworkers are incorrect, and not consistent with the calculated negative values for the excess molar volumes. In the case of negative excess molar volumes the apparent molar volumes of the mixture components must be less than the molar volumes of the neat mixture co-solvents. This is not the case with the apparent molar volumes given in the published paper.
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