Abstract

A large body of work on the algebraic properties of the Gelfand labelling scheme for atoms with several electrons has recently been synthesized by Harter (see abstr. A31652 of 1974) into a compact procedure for the construction of total angular momentum eigenfunctions and the evaluation of angular coefficients. Certain ambiguities in the procedure are removed. Also, an improved method for the diagonalization of the angular momentum matrix in the Galfand basis set is presented. As an example, the doublet states of the f3 configuration are discussed.

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