Abstract

The scaling theory used to analyze the results of recent Monte Carlo simulations of a three-dimensional critical wetting transition is reexamined. It is shown that the scaling form of the surface-layer susceptibility ${\ensuremath{\chi}}_{1}$ suggested in the earlier analyses is not always consistent with an exact thermodynamic requirement. A consistent scaling form for ${\ensuremath{\chi}}_{1}$ is introduced and used to derive relationships between the thickness of the wetting film $l$, the transverse correlation length ${\ensuremath{\xi}}_{\ensuremath{\parallel}}$, and the surface roughness ${\ensuremath{\xi}}_{\ensuremath{\perp}}$. These relationships are consistent with the results of renormalization-group calculations. The present procedure avoids introducing specific (nontrivial) corrections to the standard scaling ansatz for the singular contribution to the surface excess free energy.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call