Abstract
The soft zone-center ${E}_{2u}$ mode was recently observed by means of hyper-Raman scattering by Inoue et al. [Phys. Rev. B 38, 6352 (1988)]. Knowing that the ${E}_{2u}$ mode drives the transition, we obtain the lower-symmetry space group of the transition, construct the free energy (including elastic coupling), and show the possible optical modes allowed by symmetry.
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