Abstract

AbstractWe argue that the 3A2 state considered by Oleś in phys. stat. sol. (b) 236, 281 (2003) for the d2 system occurring in the V3+ ion in V2O3 and LaVO3 as well as in the Ti2+ ion in TiO and in many other oxides is wrong. The proper ground state is 3T1g – its 9‐fold degeneracy is further split in a crystal by intra‐atomic spin–orbit interactions and lattice distortions. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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