Comment on egusphere-2022-226

Abstract

We implement the GEOS-Chem chemistry module as a chemical mechanism in the Community Earth System Model version 2 (CESM). Our implementation allows the state-of-the-science GEOS-Chem chemistry module to be used with identical emissions, meteorology, and climate feedbacks as the CAM-chem chemistry module within CESM. We use coupling interfaces to allow GEOS-Chem to operate almost unchanged within CESM. Aerosols are converted at each time step between the GEOS-Chem bulk representation and the size-resolved representation of CESM’s Modal Aerosol Model (MAM4). Land type information needed for dry deposition calculations in GEOS-Chem is communicated through a coupler, allowing online land-atmosphere interactions. Wet scavenging in GEOS-Chem is replaced with the Neu and Prather scheme, and a common emissions approach is developed for both CAM-chem and GEOS-Chem in CESM. We compare how GEOS-Chem embedded in CESM (C-GC) compares to the existing CAM-chem chemistry option (C-CC) when used to simulate atmospheric chemistry in 2016, with identical meteorology and emissions. We compare atmospheric composition and deposition tendencies between the two simulations and evaluate the residual differences between C-GC compared to its use as a standalone chemistry transport model (S-GC). We find that stratospheric ozone agrees well between the three models with differences of less than 10 % in the core of the ozone layer, but that ozone at lower altitudes is generally lower in C-GC than in either C-CC or S-GC due to greater tropospheric concentrations of bromine. This difference is not uniform, with C-GC ozone 30 % lower in the southern hemisphere than in S-GC but within 10 % in the northern hemisphere, suggesting differences in the effects of anthropogenic emissions. Aerosol concentrations in C-GC agree with those in S-GC at low altitudes in the tropics but are over 100 % greater in the upper troposphere due to differences in the representation of convective scavenging. We also find that water vapor concentrations vary substantially between the standalone and CESM-implemented version of GEOS-Chem, as the simulated hydrological cycle in CESM diverges from that represented in the source MERRA-2 meteorology. Our implementation of GEOS-Chem as a chemistry option in CESM (including full chemistry-climate feedbacks) is publicly available and is being considered for inclusion in the CESM main code repository. This work is a significant step in the MUlti-Scale Infrastructure for Chemistry and Aerosols (MUSICA) project, enabling two communities of atmospheric researchers (CESM and GEOS-Chem) to share expertise through a common modeling framework and thereby accelerate progress in atmospheric science.