Abstract

<strong class="journal-contentHeaderColor">Abstract.</strong> The Geostationary Environmental Monitoring Spectrometer (GEMS) is a UV&ndash;visible spectrometer onboard the GEO-KOMPSAT-2B satellite launched into geostationary orbit in February 2020. To evaluate GEMS NO<sub>2</sub> column data, comparison was carried out using NO<sub>2</sub> vertical column density (VCD) measured using direct-sunlight observations by the Pandora spectrometer system at four sites in Seosan, South Korea, during November 2020 to January 2021. Correlation coefficients between GEMS and Pandora NO<sub>2</sub> data at four sites ranged from 0.35 to 0.48, with root mean square errors (RMSEs) from 4.7 &times; 10<sup>15</sup> molec. cm<sup>-2</sup> to 5.5 &times; 10<sup>15</sup> molec. cm<sup>-2</sup> for cloud fraction (CF) &lt; 0.7. Higher correlation coefficients of 0.62&ndash;0.78 with lower RMSEs from 3.3 &times; 10<sup>15 </sup>molec. cm<sup>-2</sup> to 4.3 &times; 10<sup>15</sup> molec. cm<sup>-2</sup> were found with CF &lt; 0.3, indicating the higher sensitivity of GEMS to atmospheric NO<sub>2</sub> in less-cloudy conditions. Overall, GEMS NO<sub>2</sub> column data tend to be lower than those of Pandora due to differences in representative spatial coverage, with a large negative bias under high-CF conditions. With correction for horizontal representativeness in Pandora measurement coverage, the correlation coefficients range from 0.69 to 0.81 with RMSEs from 3.2 &times; 10<sup>15</sup> molec. cm<sup>-2</sup> to 4.9 &times; 10<sup>15</sup> molec. cm<sup>-2</sup> were achieved for CF &lt; 0.3, showing the better correlation with the correction than that without the correction.

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