Abstract

A correlation has been proposed by Urošević Panić Jovanić, Zeković and Savić between the lifetimes of Cr 3+ in various environments and the Dq parameter of ligand field theory. We show that these observed lifetimes depend on various factors such as multisite effects, reabsorption, thermal excitation or 2E 4T 2 mixing. The correlation between lifetimes and pressure on ruby has to consider these different effects.

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