Command surface induced switching of the optical properties of liquid crystalline thin film structures

Abstract

We report on optical waveguide structures with light propagation in a nematic liquid crystalline thin film. The liquid crystal (LC) is sandwiched between two so-called photochromic command layers, consisting of a polymer with azobenzene side chains. When exposed to light of appropriate wavelength, the azobenzene side chains undergo a transcis isomerization process, inducing a homeotropicparallel change in the LC alignment. These orientational changes affect the set of refractive indices of the LC thin film and, hence, can be detected by optical waveguide methods. As a possible application of the command surface effect in optical waveguide structures, we present an optical switching and information storage device.