Cometary impacts into ocean: Thermodynamical equilibrium calculations of high-temperature O2 generation on the early Earth

Abstract

The early Earth?s atmosphere apparently differed from the present atmosphere mainly in its lack of free O2, and this absence is believed to have been indispensable for the origin of early anaerobic life forms. One of the central problems in Earth science is to explain the apparent transition from the primitive atmosphere (free of O2) to the present atmosphere which contains 21% of the gas. Theoretical models suggest that the initial form of O2 in the Earth?s atmosphere may have been H2O, which was converted into atmospheric O2 mainly through photosynthesis. We have investigated an alternative (abiotic) method for the conversion of H2O to O2: a high-temperature shock generated during a cometary impact into an ocean (or on land). The calculations presented here show that 1% of the present level of O2 could have resulted from an icy 1.3x1016 kg comet entering the early (pre-oxygenic) Earth with a velocity of between about 11 and 30 km s-1.