Abstract
Preparation of the (Ti 1− x Nb x ) 2AlC solid solution (formed from the M n+1 AX n or MAX carbides, where n = 1, 2, or 3, M is an early transition metal, A is an A-group element, and X is C) with x = 0.2–0.8 was investigated by self-propagating high-temperature synthesis (SHS). Nearly single-phase (Ti,Nb) 2AlC was produced through direct combustion of constituent elements. Due to the decrease of reaction exothermicity, the combustion temperature and reaction front velocity decreased with increasing Nb content of (Ti 1− x Nb x ) 2AlC formed from the elemental powder compacts. In addition, the samples composed of Ti, Al, Nb 2O 5, and Al 4C 3 were adopted for the in situ formation of Al 2O 3-added (Ti,Nb) 2AlC. The SHS process of the Nb 2O 5/Al 4C 3-containing sample involved aluminothermic reduction of Nb 2O 5, which not only enhanced the reaction exothermicity but also facilitated the evolution of (Ti,Nb) 2AlC. Based upon the XRD analysis, two intermediates, TiC and Nb 2Al, were detected in the (Ti,Nb) 2AlC/Al 2O 3 composite and their amounts were reduced by increasing the extent of thermite reduction involved in the SHS process. The laminated microstructure characteristic of the MAX carbide was observed for both monolithic and Al 2O 3-added (Ti,Nb) 2AlC solid solutions synthesized in this study.
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