Combustion Characteristics and Kinetic Analysis of Biomass Pellet Fuel Using Thermogravimetric Analysis

Guohai Jia

doi:10.3390/pr9050868

Abstract

Biomass pellet fuel is one of the development directions of renewable energy. The purpose of the article is to study the combustion characteristics of five kinds of biomass pellet fuel that can be used as biomass fuel and analyze their combustion kinetics. The thermogravimetric method (TG method) was used to analyze the combustion characteristics of five kinds of biomass pellet fuel and to calculate the index S of comprehensive combustion characteristic. The Arrhenius equation and the Coats–Redfern method were used to analyze the combustion kinetics of five kinds of biomass pellet fuel. The activation energy and pre-exponential factor were obtained according to different temperature ranges. Conclusions are as follows: The pyrolysis of five kinds of biomass pellet fuel mainly includes three stages: (1) water evaporation stage, (2) volatile component combustion stage, (3) fixed carbon oxidation stage. The TG curves of five kinds of biomass pellet fuel are roughly the same at the same heating rate. The peaks of thermal weight loss rate and maximum degradation rate are both in the high temperature range. The differential thermal gravity (DTG) curves of five kinds of biomass pellet fuel have an obvious peak. The peak temperature of the largest peak in the DTG curves is 280–310 °C. The first-order reaction equation is used to obtain the kinetic parameters in stages. The correlation coefficients are bigger than the value of 0.92. The fitting results are in good agreement with the experimental results. The activation energy of each sample is basically the same in each stage. The value in the volatile matter combustion stage is 56–542 kJ/mol, and the activation energy of the carbon layer slowly increases rapidly. The five kinds of biomass pellet fuels have good combustion characteristics and kinetic characteristics, and they can be promoted and applied as biomass pellet fuels in the future.

Highlights

In today’s era, the calls for energy crises [1,2,3] and environmental pollution [4,5]are increasing
Stylianos et al [9] studied the pyrolysis of cellulose, hemicellulose and lignin
In the process of pyrolysis, the biomass pellet fuels are transformed to the low molecular weight gases(volatiles) and solid(char)

Summary

Introduction

The reuse of agricultural and forestry waste has become the focus of attention [6]. Crop stalks, which are abundant in resource reserves, are one of the widely used agricultural and forestry wastes. As the output of various fruit husk residues increases year by year, people have begun to pay attention to them [7]. Pyrolysis is the widely used method in converting waste biomass into valuable chemicals of biomass pellet fuels [8]. Stylianos et al [9] studied the pyrolysis of cellulose, hemicellulose and lignin. In the process of pyrolysis, the biomass pellet fuels are transformed to the low molecular weight gases(volatiles) and solid(char). Liu et al [10] studied the combustion behavior of corncob/bituminous coal and hardwood/bituminous coal. Sharma et al [11]

Objectives

Results

Conclusion