Combined processes of glycerol polymerization/carbonization/activation to produce efficient adsorbents for organic contaminants

Abstract

AbstractBACKGROUND: Glycerol was used to produce efficient adsorbents with a high surface area for organic contaminants by a combined process based on polymerization, carbonization and activation.RESULTS: Glycerol and sulfuric acid catalyst at concentrations of 0, 0.5, 1, 2 and 5 mol% were heated to 150 °C to form polyglycerol, which was then decomposed at 580 °C and activated with CO2 at 850 °C. The resulting activated carbons had a high specific area (1630 m2g−1) and high adsorption capacity of methylene blue used as a model organic contaminant. This process was also used to produce a special composite adsorbent based on expanded vermiculite (EV) coated with activated carbon. These composites were produced by impregnation of EV with glycerol followed by polymerization, thermal decomposition and activation with CO2 to produce up to 25 wt% carbon and a surface area of 835 m2g−1.CONCLUSIONS: The carbon layer present in the EV composite/activated carbon (GVE4CA2) produces a remarkable increase in the methylene blue adsorption capacity of the expanded vermiculite and strongly decreases undesirable water absorption. Copyright © 2012 Society of Chemical Industry