Abstract

Dextran-Fe 3O 4 hybrid clusters were fabricated by coprecipitating ferric and ferrous ions in the presence of dextran, and after characterization of these clusters combined with calculation based on classical nucleation theory, a structure model of these hybrid clusters was proposed. The hybrid cluster was believed including small Fe 3O 4 nanoparticles and dextran which acted as both nucleating agent and stabilizer, so that exist in both the inside of magnetite nanoparticles and the periphery of the hybrid clusters. Besides, the effects of W CD (weight iron cation:weight dextran) and molecular weight of dextran on the size, morphology and magnetic property of clusters were also investigated in this paper. It was found that the variation of W CD and molecular weight of dextran have great effect on the size of the hybrid clusters, but have almost no effect on the size of the Fe 3O 4 nanoparticles. The characterization of magnetic property demonstrated that the Fe 3O 4 nanoparticles are of a single domain and the saturation magnetization was affected by the size of dextran-Fe 3O 4 hybrid clusters.

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