Combined (alkaline + ultrasonic) pretreatment effect on sewage sludge disintegration

Abstract

The individual effects of alkaline (pH 8-13) and ultrasonic (3750–45,000 kJ/kg TS) pretreatments on the disintegration of sewage sludge were separately tested, and then the effect of combining these two methods at different intensity levels was investigated using response surface methodology (RSM). In the combined pretreatment, ultrasonic treatment was applied to the alkali-pretreated sludge. While the solubilization (SCOD/TCOD) increase was limited to 50% in individual pretreatments, it reached 70% in combined pretreatment, and the results clearly showed that preconditioning of sludge at high pH levels played a crucial role in enhancing the disintegration efficiency of the subsequent ultrasonic pretreatment. By applying regression analysis, the disintegration degree (DD) was fitted based on the actual value to a second order polynomial equation: Y = −172.44 + 29.82 X 1 + 5.30 × 10 −3 X 2 − 7.53 × 10 −5 X 1 X 2 − 1.10 X 1 2 − 1.043 × 10 −7 X 2 2, where X 1, X 2, and Y are pH, specific energy input (kJ/kg TS), and DD, respectively. In a 2D contour plot describing the tendency of DD with respect to pH and specific energy input, it was clear that DD increased as pH increased, but it seemed that DD decreased when the specific energy input exceeded about 20,000 kJ/kg TS. This phenomenon tells us that there exists a certain point where additional energy input is ineffective in achieving further disintegration. A synergetic disintegration effect was also found in the combined pretreatment, with lower specific energy input in ultrasonic pretreatment yielding higher synergetic effect. Finally, in order to see the combined pretreatment effect in continuous operation, the sludge pretreated with low intensity alkaline (pH 9)/ultrasonic (7500 kJ/kg TS) treatment was fed to a 3 L of anaerobic sequencing batch reactor after 70 days of control operation. CH 4 production yield significantly increased from 81.9 ± 4.5 mL CH 4/g COD added to 127.3 ± 5.0 mL CH 4/g COD added by pretreatment, and this enhanced performance was closely related to the solubilization increase of the sludge by pretreatment. However, enhanced anaerobic digestion resulted in 20% higher soluble N concentration in the reactor, which would be an additional burden in the subsequent nitrogen removal system.