Combinatorial Methods in Catalysis and Materials Science

Abstract

AbstractThe article contains sections titled:1.Introduction2.Enzyme Mimetics and Metal Complexes as Enzyme Mimetics2.1.Combinatorial Libraries of Catalysts as Enzyme Mimetics2.2.Combinatorial Synthesis Enzyme Mimetics2.2.1.Hydrolytically Active Metal Complexes2.2.2.Evolutionary Solid‐Phase Synthesis of Oxygenase Mimics2.2.3.Libraries of Organic Acylation Catalysts3.Combinatorial Catalysis in Asymmetric Synthesis3.1.Combinatorial Catalyst Libraries in Enantioselective Additions of Dialkylzinc Reagents3.2.Ligands for the Lewis Acid‐Catalyzed Asymmetric Aza Diels ‐ Alder Reaction3.3.Divergent Ligand Synthesis for Enantioselective Alkylations3.4.Chiral Phosphine Ligands for Asymmetric Hydrogenation3.5.Asymmetric Reactions Catalyzed by Schiff Base‐Type Ligands: the Positional Scanning Approach3.6.Identification of Novel Catalysts for Asymmetric Epoxidations by the Positional Scanning Approach4.Multidimensional Combinatorial Screening for the Identification of Novel Catalysts4.1.Catalyst Discovery and Optimization Using Catalyst Arrays4.2.Parallel Array Screening for Catalyst Optimization Using Discovery and Focused Ligand Libraries5.One‐Pot, Multi‐Substrate Screening6.Combinatorial Approaches to Olefin Polymerization Catalysts7.Combinatorial Inorganic Catalysis7.1.Combinatorial Libraries of Homogeneous Polyoxometalate‐Based Catalysts7.2.Combinatorial Libraries and High‐Throughput Screening of Heterogenous Polyoxometalate Catalysts8.Combinatorial Heterogeneous Catalysis8.1.Oxidative Dehydrogenation of Ethane8.2.Oxidative Dehydrogenation of Propane8.3.Catalytic Oxidation of CO and Reduction of NO9.Combinatorial Electrocatalysis9.1.Electrocatalysts for Fuel Cells9.2.Combinatorial Electrosynthesis10.High‐throughput Screening Tools for Catalysis11.Combinatorial Solid‐State Materials Science11.1.Materials Library Synthesis11.1.1.Vapor Deposition Techniques11.1.2.Alternative Library Synthesis Techniques11.2.High‐Throughput Screening for Materials11.2.1.Optical Screening11.2.2.X‐Ray Characterization11.3.Applications of Materials11.3.1.Superconductivity11.3.2.Ferromagnetic Semiconductors11.3.3.Magnetoresistant Materials11.3.4.Dielectric and Ferroelectric Materials11.3.5.Luminescent Materials12.Organic Materials and Polymers12.1.Schiff Bases for Nonlinear Optical (NLO) Materials12.2.Artificial Receptors for Small Organic Molecules12.3.New Materials for the Separation of Enantiomers12.4.Molecular Imprinting12.5.Polymer Topologies and Functionalization13.Summary and Outlook