Abstract
To handle complex wastewater with limited biodegradability, hybrid treatment systems are necessary. The current study represents the combined effectiveness of sulfate-radical associated electro-chemical advanced oxidation process (SR-EAOP) and electro-coagulation (EC) for the treatment of stabilized landfill leachate. For SR-EAOP, Pt/Ti was employed as the anode and an iron plate as the cathode; while EC treatment was performed by switching the polarity. Hence, both electrochemical treatment was carried out in single reactor. Initially, the effects of pH, applied voltage, persulfate and Fe2+ dosage, on the performance of SR-EAOP was examined. Sulfate radical was generated in the electrolytic system via cathodic reduction of persulfate (PS) and ferrous (Fe2+) ion activation. Auxiliary processes such as anodic oxidation via Pt/Ti anode and indirect electro-chemical oxidation were also contributed for pollutant degradation. Combined process SR-EAOP followed by EC (SR-EAOP + EC) has better leachate treatment efficacy in comparison with EC + SR-EAOPs. The SR-EAOP + EC based combined treatment mechanism achieved an efficient COD reduction of 88.67% than that of EC + SR – EAOP process (74.51% COD reduction). Characterization studies have been carried out for post-treated dried-sludge using Field Emission scanning electron microscope (FE-SEM) and X-ray powder diffraction (XRD) techniques. The combined process treatment (SR-EAOP + EC) can be applied as pre-treatment for leachate decontamination.
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