Combination mechanism of the ternary composite based on Fe3O4-chitosan-graphene oxide prepared by solvothermal method

Abstract

Magnetic nanohybrid combining chitosan and graphene have demonstrated promising application in environmental remediation. Herein, ternary composite MCG based on Fe3O4, chitosan (CS) and graphene oxide (GO) was facilely prepared via solvothermal method. The as prepared composite was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), Raman, Brunauer/Emmett/Teller-Barret/Joyner/Halenda (BET-BJH) and thermo gravimetric-differential thermal analysis (TG-DTA). The combination mechanism of MCG was unveiled via employing the hard-soft acid-base (HSAB) theory and spectroscopic investigations including X-ray photoelectron spectroscopy (XPS), Ultraviolet–visible (UV–Vis) and fluorescent emission spectra. Particularly, combination mechanism of MCG was elucidated by the probable site to site interaction of the couplet components in MCG, as follows. (1) CS-Fe3O4. The primary interaction is N(NH2)-Fe(III), electron donates from N to Fe, transforming one half of the amino groups of chitosan into positive N+. (2) GO-CS. Amidation reaction is the primary interaction form, converting the other half of the amino groups of chitosan into –C(O)NH–. (3) GO-Fe3O4. Dominant interactions are those of epoxy, hydroxyl and aromatic ring with Fe(III). Moreover, MCG exhibits fair adsorption performance on divalent heavy metals in six consecutive cycles. These explorations may shed light on the design of efficient adsorbent based on Fe3O4-chitosan-graphene architecture.