Abstract
We present here a systematic analysis of the influence of Tm3+ doping concentrations (xTm) on the excitation power (P)-dependent upconversion luminescence and -performance of hexagonal-phase NaYF4: 20% Yb3+, xTm % Tm3+ upconversion nanoparticles (UCNPs) for xTm of 0.2, 0.5, 0.8, 1.2, and 2.0, respectively. Our results reveal the influence of these different Tm3+ doping concentrations with respect to optimized upconversion quantum yield (ΦUC) values of the various Tm3+ upconversion emission bands, with the highest ΦUC values of the Tm3+ emission bands above 700 nm resulting for different xTm values as the Tm3+ emission bands below 700 nm. This underlines the potential of Tm3+ dopant concentration for colour tuning. Special emphasis was dedicated to the spectroscopic parameters that can be linked to the (de)population pathways of the various Tm3+ energy levels, like the P- and xTm-dependent slope factors and the intensity ratios of selected emission bands. The evaluation of all parameters indicates that not only energy transfer upconversion-, but also cross-relaxation processes between neighbouring Tm3+ ions play a vital role in the (de)population of the excited energy levels of Yb3+, Tm3+ codoped nanocrystals.
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