Abstract

Tunable up-conversion luminescent material KY(MoO4)2: Yb3+, Ln3+ (Ln=Er, Tm, Ho) has been synthesized by a typical hydrothermal process. Under 980nm laser diode (LD) excitation, the emission intensity and the corresponding luminescence colors of KY(MoO4)2: Yb3+, Ln3+ (Ln=Er, Tm, Ho) have been investigated in detail. The energy transfer from the Yb3+ sensitizer to Ho3+, Er3+ and Tm3+ activators plays an important role in the development of color-tunable single- phased phosphors. The emission intensity keep balance through control of the Ho3+ co-doping concentrations, white light was experimentally shown at KY(MoO4)2: 20mol% Yb3+, 0.8mol% Er3+, 0.5mol% Tm3+, 1.0mol% Ho3+ phosphor with further calcination at 800°C for 4h under 980nm laser excitation. The color tunability, high quality of white light and high intensity of the emitted signal make these up-conversion (UC) phosphors excellent candidates for applications in solid-state lighting.

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